Nylon is a generic designation for a family of synthetic polymers Synthetic polymers are often referred to as "plastics", such as the well-known polyethylene and nylon. However, most of them can be classified in at least three main categories: thermoplastics, thermosets and elastomers known generically as polyamides A polyamide is a polymer containing monomers of amides joined by peptide bonds. They can occur both naturally and artificially, examples being proteins, such as wool and silk, and can be made artificially through step-growth polymerization, examples being nylons, aramids, and sodium poly. Polyamides are commonly used in textiles, automotives,, first produced on February 28, 1935 by Wallace Carothers Wallace Hume Carothers was an American chemist, inventor and the leader of organic chemistry at DuPont, credited with the invention of nylon at DuPont E. I. du Pont de Nemours and Company , commonly referred to as DuPont or Du Pont, is an American chemical company that was founded in July 1802 as a gunpowder mill by Eleuthère Irénée du Pont. DuPont is currently the world's second largest chemical company (behind BASF) in terms of market capitalization and fourth (behind BASF, Dow Chemical and's research facility at the DuPont Experimental Station. Nylon is one of the most commonly used polymers.

Contents

Overview

Nylon is a thermoplastic A thermoplastic, also known as thermosoftening plastic, is a polymer that turns to a liquid when heated and freezes to a very glassy state when cooled sufficiently. Most thermoplastics are high-molecular-weight polymers whose chains associate through weak Van der Waals forces ; stronger dipole-dipole interactions and hydrogen bonding (nylon); or silky material, first used commercially in a nylon-bristled A bristle is a stiff hair or feather. Also used are synthetic materials such as nylon in items such as brooms and sweepers. Bristles are often used to make brushes for cleaning uses, as they are strongly abrasive; common examples include the toothbrush and toilet brush. The bristle brush is a common household cleaning tool, often used to remove toothbrush The toothbrush is an instrument consisting of a small brush on a handle used to clean teeth through tooth brushing. Toothpaste, often containing fluoride, is commonly added to a toothbrush. Toothbrushes are offered with varying textures of bristles, and come in many different sizes and forms. Most dentists recommend using a toothbrush labelled & (1938), followed more famously by women's stockings A stocking, sometimes referred to as hose, is a close-fitting, variously elastic garment covering the foot and lower part of the leg. Stockings vary in color, design and transparency. By analogy, the term is also used to describe a type of horse marking in which the white coloring extends from the horse's hoof to just above the knee ("nylons"; 1940). It is made of repeating units A polymer is a large molecule composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a wide variety of properties linked by peptide bonds This article is for the peptide link found within biological molecules, such as proteins. A similar article for synthetic molecules is being created. Be aware that, although the atoms involved are the same, the terms amide link and peptide link cannot be used interchangedly (or amide In chemistry, an amide is usually an organic compound that contains the functional group consisting of an acyl group linked to a nitrogen atom (N). The term refers both to a class of compounds and a functional group within those compounds. The term amide also refers to deprotonated form of ammonia (NH3) or an amine, often represented as anions R2N- bonds A chemical bond is an attraction between atoms or molecules and allows the formation of chemical compounds, which contain two or more atoms. A chemical bond is the attraction caused by the electromagnetic force between opposing charges, either between electrons and nuclei, or as the result of a dipole attraction. The strength of bonds varies) and is frequently referred to as polyamide A polyamide is a polymer containing monomers of amides joined by peptide bonds. They can occur both naturally and artificially, examples being proteins, such as wool and silk, and can be made artificially through step-growth polymerization, examples being nylons, aramids, and sodium poly. Polyamides are commonly used in textiles, automotives, (PA). Nylon was the first commercially Commerce is a division of trade or production which deals with the exchange of goods and services from producer to final consumer OR commerce is the exchange of goods and services from the point of production to the point of consumption to satisfy human wants. It comprises the trading of something of economic value such as goods, services, successful synthetic polymer. There are two common methods of making nylon for fiber applications. In one approach, molecules with an acid (COOH) group on each end are reacted with molecules containing amine (NH2) groups on each end. The resulting nylon is named on the basis of the number of carbon atoms separating the two acid groups and the two amines. These are formed into monomers A monomer is an atom or a small molecule that may bind chemically to other monomers to form a polymer or cluster[citation needed]. The most common natural monomer is glucose, which is linked by glycosidic bonds into polymers such as cellulose and starch, and is over 76% of the weight of all plant matter of intermediate molecular weight The molecular mass of a substance is the mass of one molecule of that substance, in unified atomic mass unit(s) u (equal to 1/12 the mass of one isotope of carbon-12). This is numerically equivalent to the relative molecular mass of a molecule, frequently referred to by the term molecular weight and abbreviated as MW, which is the ratio of the, which are then reacted to form long polymer A polymer is a large molecule composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a wide variety of properties chains.

Nylon was intended to be a synthetic replacement for silk Silk is a natural protein fibre, some forms of which can be woven into textiles. The best-known type of silk is obtained from the cocoons of the larvae of the mulberry silkworm Bombyx mori reared in captivity . The shimmering appearance of silk is due to the triangular prism-like structure of the silk fibre, which allows silk cloth to refract and substituted for it in many different products after silk became scarce during World War II Albania · Australia · Austria · Azerbaijan · Belarus · Belgium · Brazil · Bulgaria · Burma · Cambodia · Canada · Ceylon (Sri Lanka) · Channel Islands · China · Czechoslovakia · Denmark · Dutch East Indies · Egypt · Estonia · Finland · France · Germany · Gibraltar · Greece · Greenland · Hong Kong · Hungary · Iceland ·. It replaced silk in military applications such as parachutes A parachute is a device used to slow the motion of an object through an atmosphere by creating drag. Parachutes are usually made out of cloth, most commonly nylon. Parachutes must slow an object's terminal vertical speed by a minimum 75% in order to be classified as such and flak vests A flak jacket or flak vest is a form of protective clothing designed to provide protection from shrapnel and other indirect low velocity projectiles. Today it frequently refers to ballistic vests, particularly Type III and above, which have added steel, titanium, ceramic or polyethylene plates which can withstand high-powered rounds such as those, and was used in many types of vehicle tires.

Nylon fibres are used in many applications, including fabrics A textile is a flexible material consisting of a network of natural or artificial fibres often referred to as thread or yarn. Yarn is produced by spinning raw wool fibres, linen, cotton, or other material on a spinning wheel to produce long strands. Textiles are formed by weaving, knitting, crocheting, knotting, or pressing fibres together, bridal veils, carpets, musical strings, and rope A rope is a length of fibres, twisted or braided together to improve strength for pulling and connecting. It has tensile strength but is too flexible to provide compressive strength . Rope is thicker and stronger than similarly constructed cord, line, string, and twine.

Solid nylon is used for mechanical A machine is a device that uses energy to perform some activity. In common usage, the meaning is that of a device having parts that perform or assist in performing any type of work. A simple machine is a device that transforms the direction or magnitude of a force without consuming any energy. The word "machine" is derived from the Latin parts such as machine screws, gears A gear is a rotating machine part having cut teeth, or cogs, which mesh with another toothed part in order to transmit torque. Two or more gears working in tandem are called a transmission and can produce a mechanical advantage through a gear ratio and thus may be considered a simple machine. Geared devices can change the speed, magnitude, and and other low- to medium-stress components previously cast in metal. Engineering-grade nylon is processed by extrusion, casting, and injection molding Injection molding is a manufacturing process for producing parts from both thermoplastic and thermosetting plastic materials. Material is fed into a heated barrel, mixed, and forced into a mold cavity where it cools and hardens to the configuration of the mold cavity. After a product is designed, usually by an industrial designer or an engineer,. Solid nylon is used in hair combs. Type 6,6 Nylon 101 is the most common commercial grade of nylon, and Nylon 6 is the most common commercial grade of molded nylon. Nylon is available in glass-filled variants which increase structural and impact strength and rigidity, and molybdenum sulfide-filled variants which increase lubricity Lubricity is the measure of the reduction in friction of a lubricant. The study of lubrication and mechanism wear is called tribology.

Aramids Aramid fibers are a class of heat-resistant and strong synthetic fibers. They are used in aerospace and military applications, for ballistic rated body armor fabric, in bicycle tires, and as an asbestos substitute. The name is a shortened form of "aromatic polyamide". They are fibers in which the chain molecules are highly oriented along are another type of polyamide with quite different chain structures which include aromatic In organic chemistry, the structures of some rings of atoms are unexpectedly stable. Aromaticity is a chemical property in which a conjugated ring of unsaturated bonds, lone pairs, or empty orbitals exhibit a stabilization stronger than would be expected by the stabilization of conjugation alone. It can also be considered a manifestation of cyclic groups in the main chain. Such polymers make excellent ballistic A ballistic body is a body which is free to move, behave, and be modified in appearance, contour, or texture by ambient conditions, substances, or forces, as by the pressure of gases in a gun, by rifling in a barrel, by gravity, by temperature, or by air particles. A ballistic missile is a missile only guided during the relatively brief initial fibres.

Chemistry

Nylons are condensation copolymers Condensation polymers are any kind of polymers formed through a condensation reaction, releasing small molecules as by-products such as water or methanol, as opposed to addition polymers which involve the reaction of unsaturated monomers. Types of condensation polymers include polyamides, polyacetals and polyesters formed by reacting equal parts of a diamine and a dicarboxylic acid Dicarboxylic acids are organic compounds that are substituted with two carboxylic acid functional groups. In molecular formulae for dicarboxylic acids, these groups are often written as HOOC-R-COOH, where R is usually an alkyl, alkenyl, or akynyl group. Dicarboxylic acids can be used to prepare copolymers such as nylon and polyethylene, so that peptide bonds This article is for the peptide link found within biological molecules, such as proteins. A similar article for synthetic molecules is being created. Be aware that, although the atoms involved are the same, the terms amide link and peptide link cannot be used interchangedly form at both ends of each monomer in a process analogous to polypeptide Peptides are short polymers of amino acids linked by peptide bonds. They have the same chemical structure as proteins, but only shorter in length biopolymers Biopolymers are polymers produced by living organisms. Cellulose, starch and chitin, proteins and peptides, and DNA and RNA are all examples of biopolymers, in which the monomeric units, respectively, are sugars, amino acids, and nucleotides. Chemical elements A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. The term is also used to refer to a pure chemical substance composed of atoms with the same number of protons. Common examples of elements are iron, copper, silver, gold, hydrogen, carbon, included are carbon Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds. There are three naturally occurring isotopes, with 12C and 13C being stable, while 14C is radioactive, decaying with a half-life of, hydrogen Hydrogen is the chemical element with atomic number 1. It is represented by the symbol H. With an average atomic weight of 1.00794 u (1.007825 u for Hydrogen-1), hydrogen is the lightest and most abundant chemical element, constituting roughly 75 % of the Universe's elemental mass. Stars in the main sequence are mainly composed of hydrogen in its, nitrogen Nitrogen is a chemical element that has the symbol N, atomic number of 7 and atomic mass 14.00674 u. Elemental nitrogen is a colorless, odorless, tasteless and mostly inert diatomic gas at standard conditions, constituting 78.08% by volume of Earth's atmosphere, and oxygen Oxygen (pronounced /ˈɒksɨdʒɨn/, OK-si-jin, from the Greek roots ὀξύς (acid, literally "sharp", from the taste of acids) and -γενής (-genēs) (producer, literally begetter), is the element with atomic number 8 and represented by the symbol O. It is a member of the chalcogen group on the periodic table, and is a highly. The numerical suffix specifies the numbers of carbons Carbon is the chemical element with symbol C and atomic number 6. As a member of group 14 on the periodic table, it is nonmetallic and tetravalent—making four electrons available to form covalent chemical bonds. There are three naturally occurring isotopes, with 12C and 13C being stable, while 14C is radioactive, decaying with a half-life of donated by the monomers; the diamine first and the diacid second. The most common variant is nylon 6-6 which refers to the fact that the diamine (hexamethylene diamine Hexamethylenediamine is the organic compound with the formula H2N6NH2. The molecule is a diamine, consisting of a hexamethylene hydrocarbon chain terminated with amine functional groups. The colorless solid (yellowish for some commercial samples) has a strong amine odor, similar to piperidine. About 1 billion kilograms are produced annually, IUPAC The International Union of Pure and Applied Chemistry , pronounced /ˈaɪjuːpæk/, is an international federation of National Adhering Organizations that represents chemists in individual countries. It is a member of the International Council for Science (ICSU). The international headquarters of IUPAC is located in Zürich, Switzerland. The name: 1,6-diaminohexane) and the diacid (adipic acid Adipic acid is the organic compound with the formula 4(COOH)2. From the industrial perspective, it is the most important dicarboxylic acid: About 2.5 billion kilograms of this white crystalline powder are produced annually, mainly as a precursor for the production of nylon. Adipic acid otherwise rarely occurs in nature, IUPAC The International Union of Pure and Applied Chemistry , pronounced /ˈaɪjuːpæk/, is an international federation of National Adhering Organizations that represents chemists in individual countries. It is a member of the International Council for Science (ICSU). The international headquarters of IUPAC is located in Zürich, Switzerland. The name: hexane-1,6-dicarboxylic acid) each donate 6 carbons to the polymer chain. As with other regular copolymers A heteropolymer or copolymer is a polymer derived from two monomeric species, as opposed to a homopolymer where only one monomer is used. Copolymerization refers to methods used to chemically synthesize a copolymer like polyesters Polyester is a category of polymers which contain the ester functional group in their main chain. Although there are many polyesters, the term "polyester" as a specific material most commonly refers to polyethylene terephthalate . Polyesters include naturally-occurring chemicals, such as in the cutin of plant cuticles, as well as and polyurethanes A polyurethane is any polymer consisting of a chain of organic units joined by urethane (carbamate) links. Polyurethane polymers are formed through step-growth polymerization by reacting a monomer containing at least two isocyanate functional groups with another monomer containing at least two hydroxyl (alcohol) groups in the presence of a, the "repeating unit" consists of one of each monomer, so that they alternate in the chain. Since each monomer in this copolymer has the same reactive group A chemical reaction is a process that leads to the transformation of one set of chemical substances to another. Chemical reactions can be either spontaneous, requiring no input of energy, or non-spontaneous, often coming about only after the input of some type of energy, viz. heat, light or electricity. Classically, chemical reactions encompass on both ends, the direction of the amide bond This article is for the peptide link found within biological molecules, such as proteins. A similar article for synthetic molecules is being created. Be aware that, although the atoms involved are the same, the terms amide link and peptide link cannot be used interchangedly reverses between each monomer, unlike natural polyamide proteins which have overall directionality: C terminalN terminal. In the laboratory, nylon 6-6 can also be made using adipoyl chloride instead of adipic. It is difficult to get the proportions exactly correct, and deviations can lead to chain termination at molecular weights less than a desirable 10,000 daltons (u). To overcome this problem, a crystalline, solid "nylon salt" can be formed at room temperature, using an exact 1:1 ratio of the acid and the base to neutralize each other. Heated to 285 °C, the salt reacts to form nylon polymer. Above 20,000 daltons, it is impossible to spin the chains into yarn, so to combat this, some acetic acid is added to react with a free amine end group during polymer elongation to limit the molecular weight. In practice, and especially for 6,6, the monomers are often combined in a water solution. The water used to make the solution is evaporated under controlled conditions, and the increasing concentration of "salt" is polymerized to the final molecular weight.

DuPont patented[1] nylon 6,6, so in order to compete, other companies (particularly the German BASF) developed the homopolymer nylon 6, or polycaprolactam — not a condensation polymer, but formed by a ring-opening polymerization (alternatively made by polymerizing aminocaproic acid). The peptide bond within the caprolactam is broken with the exposed active groups on each side being incorporated into two new bonds as the monomer becomes part of the polymer backbone. In this case, all amide bonds lie in the same direction, but the properties of nylon 6 are sometimes indistinguishable from those of nylon 6,6 — except for melt temperature (N6 is lower) and some fiber properties in products like carpets and textiles. There is also nylon 9.

Nylon 5,10, made from pentamethylene diamine and sebacic acid, was studied by Carothers even before nylon 6,6 and has superior properties, but is more expensive to make. In keeping with this naming convention, "nylon 6,12" (N-6,12) or "PA-6,12" is a copolymer of a 6C diamine and a 12C diacid. Similarly for N-5,10 N-6,11; N-10,12, etc. Other nylons include copolymerized dicarboxylic acid/diamine products that are not based upon the monomers listed above. For example, some aromatic nylons are polymerized with the addition of diacids like terephthalic acid (→ Kevlar Twaron) or isophthalic acid (→ Nomex), more commonly associated with polyesters. There are copolymers of N-6,6/N6; copolymers of N-6,6/N-6/N-12; and others. Because of the way polyamides are formed, nylon would seem to be limited to unbranched, straight chains. But "star" branched nylon can be produced by the condensation of dicarboxylic acids with polyamines having three or more amino groups.

The general reaction is:

A molecule of water is given off and the nylon is formed. Its properties are determined by the R and R' groups in the monomers. In nylon 6,6, R = 4C and R' = 6C alkanes, but one also has to include the two carboxyl carbons in the diacid to get the number it donates to the chain. In Kevlar, both R and R' are benzene rings.

Concepts of nylon production

The first approach: combining molecules with an acid (COOH) group on each end are reacted with two chemicals that contain amine (NH2) groups on each end. This process creates nylon 6,6, made of hexamethylene diamine with six carbon atoms and adipic acid.

The second approach: a compound has an acid at one end and an amine at the other and is polymerized to form a chain with repeating units of (-NH-[CH2]n-CO-)x. In other words, nylon 6 is made from a single six-carbon substance called caprolactam. In this equation, if n=5, then nylon 6 is the assigned name (may also be referred to as polymer).

The characteristic features of nylon 6,6 include:

On the other hand, nylon 6 is easy to dye, more readily fades; it has a higher impact resistance, a more rapid moisture absorption, greater elasticity and elastic recovery.

Characteristics

Bulk properties

Above their melting temperatures, Tm, thermoplastics like nylon are amorphous solids or viscous fluids in which the chains approximate random coils. Below Tm, amorphous regions alternate with regions which are lamellar crystals.[1] The amorphous regions contribute elasticity and the crystalline regions contribute strength and rigidity. The planar amide (-CO-NH-) groups are very polar, so nylon forms multiple hydrogen bonds among adjacent strands. Because the nylon backbone is so regular and symmetrical, especially if all the amide bonds are in the trans configuration, nylons often have high crystallinity and make excellent fibers. The amount of crystallinity depends on the details of formation, as well as on the kind of nylon. Apparently it can never be quenched from a melt as a completely amorphous solid.

Nylon 6,6 can have multiple parallel strands aligned with their neighboring peptide bonds at coordinated separations of exactly 6 and 4 carbons for considerable lengths, so the carbonyl oxygens and amide hydrogens can line up to form interchain hydrogen bonds repeatedly, without interruption. Nylon 5,10 can have coordinated runs of 5 and 8 carbons. Thus parallel (but not antiparallel) strands can participate in extended, unbroken, multi-chain β-pleated sheets, a strong and tough supermolecular structure similar to that found in natural silk fibroin and the β-keratins in feathers. (Proteins have only an amino acid α-carbon separating sequential -CO-NH- groups.) Nylon 6 will form uninterrupted H-bonded sheets with mixed directionalities, but the β-sheet wrinkling is somewhat different. The three-dimensional disposition of each alkane hydrocarbon chain depends on rotations about the 109.47° tetrahedral bonds of singly-bonded carbon atoms.

When extruded into fibers through pores in an industrial spinneret, the individual polymer chains tend to align because of viscous flow. If subjected to cold drawing afterwards, the fibers align further, increasing their crystallinity, and the material acquires additional tensile strength.[2] In practice, nylon fibers are most often drawn using heated rolls at high speeds.

Block nylon tends to be less crystalline, except near the surfaces due to shearing stresses during formation. Nylon is clear and colorless, or milky, but is easily dyed. Multistranded nylon cord and rope is slippery and tends to unravel. The ends can be melted and fused with a heat source such as a flame or electrode to prevent this.

When dry, polyamide is a good electrical insulator. However, polyamide is hygroscopic. The absorption of water will change some of the material's properties such as its electrical resistance. Nylon is less absorbent than wool or cotton.

Historical uses

Bill Pittendreigh, DuPont, and other individuals and corporations worked diligently during the first few months of World War II to find a way to replace Asian silk and hemp with nylon in parachutes. It was also used to make tires, tents, ropes, ponchos, and other military supplies. It was even used in the production of a high-grade paper for U.S. currency. At the outset of the war, cotton accounted for more than 80% of all fibers used and manufactured, and wool fibers accounted for the remaining 20%. By August 1945, manufactured fibers had taken a market share of 25% and cotton had dropped.

Some of the terpolymers based upon nylon are used every day in packaging. Nylon has been used for meat wrappings and sausage sheaths.

Use in composites

Nylon can be used as the matrix material in composite materials, with reinforcing fibres like glass or carbon fiber, and has a higher density than pure nylon. Such thermoplastic composites (25% glass fibre) are frequently used in car components next to the engine, such as intake manifolds, where the good heat resistance of such materials makes them feasible competitors to metals.

Hydrolysis and degradation

All nylons are susceptible to hydrolysis, especially by strong acids, a reaction essentially the reverse of the synthetic reaction shown above. The molecular weight of nylon products so attacked drops fast, and cracks form quickly at the affected zones. Lower members of the nylons (such as nylon 6) are affected more than higher members such as nylon 12. This means that nylon parts cannot be used in contact with sulfuric acid for example, such as the electrolyte used in lead-acid batteries. When being molded, nylon must be dried to prevent hydrolysis in the molding machine barrel since water at high temperatures can also degrade the polymer. The reaction is of the type:

Incineration and recycling

Various nylons break down in fire and form hazardous smoke, and toxic fumes or ash, typically containing hydrogen cyanide. Incinerating nylons to recover the high energy used to create them is usually expensive, so most nylons reach the garbage dumps, decaying very slowly[3]. Some recycling is done on nylon, usually creating pellets for reuse in the industry, but this is done at a much lower scale[4].

Etymology

In 1940, John W. Eckelberry of DuPont stated that the letters "nyl" were arbitrary and the "on" was copied from the suffixes of other fibers such as cotton and rayon. A later publication by DuPont explained that the name was originally intended to be "No-Run" ("run" meaning "unravel"), but was modified to avoid making such an unjustified claim and to make the word sound better.[5] An apocryphal tale is that Nylon is a conflation of "New York" and "London". Equally spurious is the backronym for "Now You've Lost, Old Nippon" referring to the supposed loss of demand for Japanese silk.

See also

References

  1. ^ History of Nylon US Patent 2,130,523 'Linear polyamides suitable for spinning into strong pliable fibers', U.S. Patent 2,130,947 'Diamine dicarboxylic acid salt' and U.S. Patent 2,130,948 'Synthetic fibers', all issued September 20, 1938
  2. ^ Millimeter-wave, terahertz, and mid-infrared transmission through common clothing Appl. Phys. Lett. 85, 519 (2004); doi:10.1063/1.1771814
  3. ^ Typically 80 to 100% is sent to landfill or garbage dumps, while less than 18% are incinerated while recovering the energy. See Handbook of Plastics Recycling at Google Books.
  4. ^ Typically one percent or less of nylons are recycled this way.
  5. ^ Context, vol. 7, no. 2, 1978

Further reading

External links

For historical perspectives on nylon, see the Documents List of "The Stocking Story: You Be The Historian" at the Smithsonian website, by The Lemelson Center for the Study of Invention and Innovation, National Museum of American History, Smithsonian Institution.

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Lionel Louke

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Having studied music in Paris and Boston, Loueke tips his hat to jazz masters now and then, but the combination of his African roots, nylon string guitars ...

Jazz guitarist Lionel Loueke stays true to his African roots Washington Post



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Sat Jul 17 01:24:11 2010
POP BOTTLES - NYLON MAGAZINE
nylonmag.com
POP BOTTLES - NYLON MAGAZINE

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hu, 22 Jul 2010 04:00:00 GM

Pop bottles. Warhol gets tipsy with Dom Perignon. Just when we think we've seen the last of limited edition, Warhol-inspired​ collections (i.e. DVF swimsuits, Bond No. 9 Perfume, etc), the foundation announces their latest partnership: A ...

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Thu Jul 29 17:08:43 2010
What shade of nylon with a brown sweater dress and brown open toe highheels?
Q. I will be painting my toes dark red based on the answers to my previous question. So what shade of nylon would you think will go best. I have every shade under the sun so please help?
Asked by bcbg_chic - Sat Feb 9 13:01:03 2008 - - 5 Answers - 0 Comments

A. cinnamin
Answered by Karen - Sat Feb 9 13:07:57 2008

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Sat Jul 24 18:04:08 2010